39557-71-6Relevant articles and documents
Crown-ether functionalised second coordination sphere palladium catalysts by molecular imprinting
Viton, Florian,White, Peter S.,Gagne, Michel R.
, p. 3040 - 3041 (2007/10/03)
Functionalisation of the second coordination sphere of a molecularly imprinted Pd complex was achieved by localising within the polymeric cavity a crown-ether receptor capable of altering the catalytic activity of the reactive site.
Synthesis of 4'-Vinylbenzo-3n-crown-n Ethers (4<=n<=10)
Talma, Auke G.,Vossen, Huib van,Sudhoelter, Ernst J. R.,Eerden, Johan van,Reinhoudt, David N.
, p. 680 - 683 (2007/10/02)
4'-Vinylbenzo-3n-crown-n ethers (4=n=10) are prepared by a "Cs-templated" cyclization reaction of catechol with dimesylates of oligoethylene glycols, acetylation of the resultant benzo-3n-crown-n ethers (4=n=10), reduction of the acyl group, and dehydration of the resultant alcohols with pyridinium tosylate.